Jung Won Lee, Jung Woo Choi, Siddheshwar Dadarao Raut, Gahyeon Lee, Kangmin Seo, Jong Hoon Joo*, Won-Chul Cho*Journal of Power Sources accepted
High operational current density is essential to achieve cost-effective water electrolysis. To meet this requirement, minimizing both ohmic and mass transport resistances within the electrolyzer is crucial. In particular, the porous transport layers (PTLs) play a pivotal role by providing efficient electron conduction paths and an optimized pore structure that enhances mass transport while reducin…
Jung Won Lee, JungWoo Choi, Min Joong Kim*, Won-Chul Cho*Chemical Engineering Journal accepted
The catalyst-coated membrane (CCM) approach offers a promising way to overcome the limitations of conventional alkaline water electrolysis (AWE), including high interfacial resistance, uneven catalyst distribution, and significant gas crossover. However, Nafion and other polymer binders for CCM often face a trade-off between catalyst-membrane adhesion and electrochemical performance due to their l…
Hae In Lee, Myung Won Seo, Dong Hyun Kim, Hyuk Choi, Ju Hyeok Lee, Mi Yoo, Min-Jae Kim, Yong-Sik Ok, Siddheshwar Dadarao Raut, Dong Hyun Lee, Hyun You Kim*, Kyubock Lee*, Won-Chul Cho*RSC Mechanochemistry accepted
Silicon carbide (SiC) is a critical material across structural, electronic, and catalytic applications; however, its conventional synthesis via the Acheson process is highly energy-intensive, operating at 2200–2400 °C with low carbon efficiency. Herein, we report a novel, solvent-free mechanochemical synthesis of mesoporous SiC using CO2 as a sustainable carbon feedstock and SiO2/Mg as earth-abund…
Asridin Dayan, DongHyun Lee, Kobra Azizi, Lars Nilausen Cleemann, Won-Chul Cho*, Dirk Henkensmeier*Advanced Energy Materials Published
A sulfonated para-PBI membrane is thermally cured at 350 °C for 120 minutes. The thus obtained cMS-PBI membrane is insoluble in hot phosphoric acid solution (< 5% soluble fraction), and is free of the known breaking points under alkaline conditions, i.e. no aromatic ether bonds, no quaternary ammonium groups, no N-alkylated neutral or positively charged imidazole groups. Indeed, a 6 months long al…
Dirk Henkensmeier,* Won-Chul Cho,* Patric Jannasch,* Jelena Stojadinovic,* Qingfeng Li,* David Aili,* and Jens Oluf Jensen*CHEMICAL REVIEWS accepted
Traditionally, alkaline water electrolysis (AWE) uses diaphragms to separate anode and cathode and is operated with 5–7 M KOH feed solutions. The ban of asbestos diaphragms led to the development of polymeric diaphragms, which are now the state of the art material. A promising alternative is the ion solvating membrane. Recent developments show that high conductivities can also be obtained in 1 M K…
Jahowa Islam, Sang-Kyung Kim, Hyun-Seok Cho, Min-Joong Kim, Won-Chul Cho, Chang-Hee KimElectrochemistry Communications Accepted
Reducing the iridium loading for the oxygen evolution reaction (OER) is one of the main challenges of polymer electrolyte membrane water electrolysis (PEMWE). This study introduces grape-like iridium nanoclusters supported on boron carbide (B4C) which increase iridium utilization compared to a non-supported iridium catalyst. A simple chemical reduction method with NaBH4 as a reducing agent was use…
Boreum Lee, Hyunjun Lee, Dongjun Lim, Boris Brigljević, Wonchul Cho, Hyun-Seok Cho, Chang-Hee Kim, Hankwon LimApplied Energy Accepted
With the growing concern about environmental issues including high CO2 emission, which is the main contributor to global warming resulting in climate change, CO2 utilization technologies have received much attention. Among diverse technologies, renewable methanol synthesis using H2 generated from the water electrolysis and the CO2 captured from various industrial processes as well as the atmospher…
Ik-Sun Kim, Hyun-Seok Cho, MinJoong Kim, Hyun-Jung Oh, Sang-Yeon Lee, Yong-Kul Lee, Changsoo Lee, Jae Hun Lee, Won Chul Cho, Sang-Kyung Kim, Jong Hoon Joo, Chang-Hee KimJournal of Materials Chemistry A Accepted
The degradation of amorphous cobalt phosphides (CoPx) as an electrocatalyst for the hydrogen evolution reaction (HER) is studied in the discontinuous operation of alkaline water electrolysis cells (AWEs). Although amorphous CoPx shows a 100-fold enhancement in HER activity over nickel, the kinetic current for the HER is decreased after discontinuous operation. Under the off condition, the cathode …
Jahowa Islam, Sang-Kyung Kim, Phan Thanh Thien, Min-Joong Kim, Hyun-Seok Cho, Won-Chul Cho, Chang-Hee Kim, Changsoo Lee, Jae Hun LeeJournal of Power Sources Accepted
Mengxue Zhang, Avanthi Deshani Igalavithana, Liheng Xu, Binoy Sarkar, Deyi Hou, Ming Zhang, Amit Bhatnagar, Won Chul Cho, Yong Sik OkCritical Reviews in Environmental Science and Technology Accepted
Won-Bi Han, Ik-Sun Kim, MinJoong Kim, Won Chul Cho, Sang-Kyung Kim, Jong Hoon Joo, Young-Woo Lee, Younghyun Cho, Hyun-Seok Cho, Chang-Hee KimElectrochimica Acta Accepted
SANG HO YEOM, YOUNG HWA YUN, SEUNGWOOK CHOI, JIHEE KWON, SECHAN LEE, JAE HUN LEE, CHANGSOO LEE, MINJOONG KIM, SANG-KYUNG KIM, SUKKEE UM, CHANG-HEE KIM, WON CHUL CHO, HYUN-SEOK CHOTransactions of the Korean hydrogen and new energy society Accepted
The porous transport layer (PTL) is essential to effectively remove oxygen and hydrogen gas from the electrode surface at high current density operation conditions. In this study, the effect of PTL with different characteristics such as pore size, pore gradient, interfacial coating was investigated by multi-layered sintered mesh. A water electrolysis single cell of active area of the 34.56 cm 2 wa…
Joungho Park, Kyung Hwan Ryu, Chang-Hee Kim, Won Chul Cho, MinJoong Kim, Jae Hun Lee, Hyun-Seok Cho, Jay H LeeApplied Energy Accpeted
Hydrogen production through water electrolysis stands as a potential remedy for the problem of curtailment, which refers to the deliberate downward adjustment of output power below capacity for the purpose of balancing supply and demand. This study demonstrates how comprehensive system modeling can be used to a priori assess the economics of producing green hydrogen from curtailed renewable energy…
Muhammad Farjad Ali, Hyun-Seok Cho, Christian Immanuel Bernäcker, Justin Albers, Choi Young-Woo, MinJoong Kim, Jae Hun Lee, Changsoo Lee, Sechan Lee, Won-Chul ChoJournal of Membrane Science Accpeted
Composite separators comprising ceramic filler and thermoplastic polymer are widely used in alkaline electrolyzers due to their stability in harsh conditions. The ceramic filler should possess high chemical stability and strong interaction with the polymer binder. TiO2 is a good filler candidate due to its hydrophilicity and potential capabilities. However, the impact of TiO2 size on composite sep…
Changsoo Lee, Kihyun Shin, Youngtae Park, Young Hwa Yun, Gisu Doo, Gi Hong Jung, MinJoong Kim, Won‐Chul Cho, Chang‐Hee Kim, Hyuck Mo Lee, Hyun You Kim, Sechan Lee, Graeme Henkelman, Hyun‐Seok ChoAdvanced Functional Materials accepted
The development of highly active and durable Ir-based electrocatalysts for the acidic oxygen evolution reaction (OER) is challenging because of the corrosive anodic conditions. Herein, IrOx/Zr2ON2 electrocatalyst is demonstrated, employing Zr2ON2 as a support material, to overcome the trade-off between the activity and stability in the OER. Zr2ON2 is selected due to its excellent electrical conduc…
Muhammad Farjad Ali, Hae In Lee, Christian Immanuel Bernäcker, Thomas Weißgärber, Sechan Lee, Sang-Kyung Kim, Won-Chul ChoPolymers Accepted
Hydrogen is nowadays considered a favorable and attractive energy carrier fuel to replace other fuels that cause global warming problems. Water electrolysis has attracted the attention of researchers to produce green hydrogen mainly for the accumulation of renewable energy. Hydrogen can be safely used as a bridge to successfully connect the energy demand and supply divisions. An alkaline water ele…
Won Chul Cho, Doyeon Lee, Chang Hee Kim, Hyun Suk Cho, Sang Done KimApplied Energy Accepted
The chemical looping strategy for hydrogen production (CLH2) offers a potentially viable option for efficient fuel conversion to hydrogen with the simultaneous capture of CO2. Typically, this process uses an iron-based composite as an oxygen carrier and syngas or methane as a fuel. The environmental and economic concerns motivate the use of abundant by-product iron oxide and the industrial off-gas…